长江流域资源与环境 >> 2010, Vol. 19 >> Issue (01): 93-.

• 生态环境 • 上一篇    下一篇

长江流域常量元素的分布特征

简慧敏1|2| 姚庆祯1|3*|张经3| 吴莹3   

  1. (1.中国海洋大学化学化工学院| 山东 青岛 266100; 2.山东检验检疫技术中心| 山东 青岛 266003; 
    3.华东师范大学河口海岸国家重点实验室| 上海 200062)
  • 出版日期:2010-01-20

DISTRIBUTION CHARACTERISTICS OF MAJOR ELEMENT IN THE CHANGJIANG RIVER

JIAN Huimin1|2| YAO Qingzhen1|3| ZHANG Jing3| WU Ying3
  

  1. (1.College of Chemistry and Chemical Engineering| Ocean University of China| Qingdao 266100| China; 
    2.Shandong Technical Center of Inspection & Quarantine| Qingdao 266007| China; 
    3.State Key Laboratory of Estuarine and Coastal Research| East China Normal University| Shanghai 200062| China)
  • Online:2010-01-20

摘要:

2003年4月到5月对长江干流及主要支流河水中常量元素(Ca 2+,K+,Na+,Mg2+,Cl-,SO2-4及碱度)进行了测定,并对常量元素的含量及影响因素进行了研究。结果表明,长江阳离子以钙为主,占阳离子总量的40%~80%;而阴离子主要为HCO-3,占阴离子总量的60%~90%;阴阳离子含量顺序为HCO-3>SO2-4>Cl-,Ca 2+>Na+ >Mg 2+>K+。长江干流及主要支流河水的常量离子主要来自于岩石的风化,主要受碳酸盐类溶解的控制,硅酸盐类的风化过程较弱。而大气沉降的影响很小,只有SO2-4受大气沉降影响较大。长江干流的Na+、Mg2+、Ca2+、HCO-3和Cl-主要来自于上游,下游只是对上游的简单稀释,而没有额外来源。与世界上其它大河相比,长江的常量离子浓度处于较高的水平;温带地区的河流河水中常量离子的含量常处于较高的水平;热带地区的河流河水中常量离子的含量相对较低。

关键词: 长江/ 常量元素/ 含量/ 分布

Abstract:

The chemistry of major elements (Ca,K,Na,Mg,Cl-,SO2-4 and alkalinity) from the Changjiang River was examined with data obtained from the main stream and its main tributaries in April 2003.HCO-3 was the most abundant anion of the Changjiang River and account for 60%~90% of total anion,concentrations of anions follows the order HCO-3>SO2-4>Cl-.Among the cations,Ca2+ was predominant and account for 40%~80% of total cation.Concentrations of cations vary in the order Ca2+>Na+>Mg2+>K+.Weathering and erosion were primary importance in affecting river chemistry,which accelerated by anthropogenic activities (e.g.farming).According to the principal composition analysis of river water,water chemistry was mainly controlled by the dissolution of calcite.Silicate weathering played a minor role in the contribution to the river fluxes,while atmosphere input of major elements to the Changjiang River was very limited.The result showed that the dissolved load of the Changjiang River relative to water discharge and in absolute terms was very high compared with other major rivers in the world.High levels of major elements were often observed in rivers in temperate climate zones,whereas rivers in tropical climate zones had abundant water discharge,but relatively low levels of major elements.

Key words: Changjiang River/ major elements/ concentration/distribution

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