长江流域资源与环境 >> 2021, Vol. 30 >> Issue (12): 2962-2971.doi: 10.11870/cjlyzyyhj202112015

• 生态环境 • 上一篇    下一篇

华阳河湖群表层沉积物磷形态及生物有效性

马金玉1 ,罗千里2 ,王文才2 ,范中亚2* ,李伟杰2 ,罗艳1   

  1. (1.南昌航空大学环境与化学工程学院, 江西 南昌 330063;2.生态环境部华南环境科学研究所, 
    国家环境保护水环境模拟与污染控制重点实验室, 广东 广州 510655)
  • 出版日期:2021-12-20 发布日期:2022-01-07

Phosphorus Forms and Bioavailability in Surface Sediments of Huayang Lakes

MA Jin-yu1, LUO Qian-li2, WANG Wen-cai2, FAN Zhong-ya2,LI Wei-jie2, LUO Yan1   

  1. (1.Nanchang Hangkong University School of Environmental and Chemical Engineering, Nanchang 330063, China; 
    2. National Key Laboratory of Water Environmental Simulation and Pollution Control, South China Institute of 
    Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China)

  • Online:2021-12-20 Published:2022-01-07

摘要: 利用SMT法研究了华阳河湖群表层沉积物中磷的赋存形态,并探讨了其影响因素及生物有效性。结果表明:华阳河湖群表层沉积物总磷(TP)含量变化在431~1 099 mg/kg之间,TP平均含量大小顺序为龙感湖>黄大湖>泊湖。无机磷(IP)约占TP的36.3%~78.8%,有机磷(OP)约占TP的18.9%~40%,IP是磷的主要赋存形态。IP中各形态磷含量的高低顺序为:铁铝结合态磷(Fe/Al-P)>钙结合态磷(Ca-P)>弱吸附态磷(Ex-P)。沉积物黏土组分与TP、IP、Fe/Al-P呈极显著正相关,粒径组成比例和沉积物TP含量也存在线性关系。通过对比有无沉水植物点位,发现沉水植物使沉积物除Ex-P外其它磷形态含量降低。与其它浅水湖泊相比,华阳河湖群中潜在的生物有效磷(BAP)含量较高,含量变化为183.2~598 mg/kg,平均占沉积物TP的47.4%,BAP含量大小顺序为龙感湖>黄大湖>泊湖,与TP含量水平一致,沉积物BAP含量与水体溶解性正磷酸盐(PO43--P)呈正相关关系。该研究基于华阳河湖群沉积物磷的赋存特征分析其生物有效性,以期为解决华阳河湖群水体总磷浓度波动成因及影响提供参考。

Abstract: Phosphorus forms and bioavailability in the surface sediments of Huayang Lakes were studied by SMT method in this article.The results showed that the total phosphorus (TP) content ranged from 431-1 099 mg/kg, and the descending order of TP content was Longgan Lake> Huangda Lake> Po Lake. Inorganic phosphorus (IP) accounted for about 36.3-78.8% of TP, and organic phosphorus (OP) accounted for about 18.9-40% of TP. IP was the main form of phosphorus. The descending order of different phosphorous forms in IP was: Fe/Al-P>Ca-P>Ex-P. The clay had a very significant positive correlation with TP, IP, Fe/Al-P, and there was also a linear relationship between the particle size and TP content. By comparing sampling points with and without submerged plants, it was found that submerged plants reduced the content of various phosphorus forms in the sediments except Ex-P. The bioavailable phosphorus (BAP) content in the Huayang Lakes was relatively high compared with other shallow lakes, which ranged from 183.2-598 mg/kg, accounting for 47.4% of the sediment TP , and the descending order of BAP content was Longgan Lake>Huangda Lake> Po Lake, consistent with the TP content, the BAP content was positively correlated with PO43--P in water. Based on the occurrence characteristics of phosphorus forms in the sediments, the study analyzed the bioavailability of phosphorus, hoping to provide references for solving the causes and effects of TP concentration fluctuations in Huayang Lakes.

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