长江流域资源与环境 >> 2017, Vol. 26 >> Issue (05): 765-770.doi: 10.11870/cjlyzyyhj201705014

• 生态环境 • 上一篇    下一篇

玻璃表面PAHs垂向分布特征与室内外对比研究

于英鹏1, 陈洪全1, 刘敏2   

  1. 1. 盐城师范学院城市与规划学院, 江苏 盐城 224051;
    2. 华东师范大学地理科学学院, 上海 200241
  • 收稿日期:2016-08-26 修回日期:2016-12-12 出版日期:2017-05-20
  • 通讯作者: 刘敏 E-mail:mliu@geo.ecnu.edu.cn
  • 作者简介:于英鹏(1985~),男,博士研究生,讲师,主要从事有机污染物多界面过程研究.E-mail:pyy.lzu@163.com
  • 基金资助:
    国家自然科学基金项目(41471060,41601594);江苏省自然科学基金项目(BK20160446);江苏省高校自然科学研究重大项目(14KJA170006)

COMPARATIVE STUDY OF VERTICAL DISTRIBUTION CHARACTERISTICS AND INDOOR AND OUTDOOR OF PAHs IN ORGANIC FILM ON WINDOW GLASS SURFACE

YU Ying-peng1, CHEN Hong-quan1, LIU Min2   

  1. 1. School of Urban and Planing, Yancheng Teachers University, Yancheng 224051, China;
    2. School of Geographic Sciences, East China Normal University, Shanghai 200241, China
  • Received:2016-08-26 Revised:2016-12-12 Online:2017-05-20
  • Supported by:
    National Natural Science Fundation of China, (41471060, 41601594);Natural Science Fundation of Jiangsu Province, (BK20160446);Major Projects of Natural Science Foundation From the Jiangsu Higher Education Institutions, (14KJA170006)

摘要: 利用GC-MS对上海市玻璃表面有机膜中PAHs浓度进行了定量分析。结果表明随着楼层的增加,10层居民楼玻璃表面PAHs浓度出现先增加后减少的趋势,最高浓度出现在3层(736 ng/m2),最低在9层(346 ng/m2);17层公寓楼PAHs浓度则是先减少后增加再减少的趋势,最高浓度出现在9层(2 338 ng/m2),最低在16层(564 ng/m2)。TOC与PAHs相关性分析暗示除TOC外,玻璃表面PAHs富集可能还受控于其他因素。10层居民楼主要以3环和4环PAHs为主;而17层公寓楼则以4环为主。玻璃外表面PAHs浓度(555 ng/m2)远高于内表面(308 ng/m2);外表面主要以Phe、Pyr、Chry、Fluo和Fl为主;内外表面低环PAHs比值接近于1,高环比值基本上低于0.6。TEQ值虽然较低,但生态风险仍不能忽视。

关键词: 多环芳烃, 玻璃表面, 垂向分布, 室内与室外

Abstract: Concentration of polycyclic aromatic hydrocarbons (PAHs) in organic film on window glass surface were quantitatively analyzed by GC-MS. The results showed that with increasing floors, the density of PAHs on the residential buildings presented an increasing-decreasing trend, where the highest and lowest density appeared on the third floors and the ninth floors, respectively. While the density of PAHs of 17 floors apartment block showed a trend with first decreasing then increasing pattern, the highest and lowest density appeared on the ninth floor and the sixteenth floor, respectively. The analysis for the relations between TOC and PAHs suggests that the abundance of PAHs on the glass surface is also influenced by other factors apart from TOC. The 10 floors residential building mainly presented 3 rings and 4 rings PAHs, while the 17 floors apartment mainly presented 4 rings PAHs. The PAHs density on the outdoor glass surface was much higher than that in the indoor surface, and the outdoor glass surface mainly presented Phe, Pyr, Chry, Fluo and Fl. The ratio of low rings PAHs on the indoor and outdoor surface was close to 1, while the ratio of high rings was almost less than 0.6. Although TEQ values were lower, but we still need to pay attention to the ecological risk of PAHs in organic film on glass surface.

Key words: polycyclic aromatic hydrocarbons(PAHs), glass surface, vertical distribution, indoor and outdoor

中图分类号: 

  • X511
[1] LIU Y,CHEN L,ZHAO J F,et al.Polycyclic aromatic hydrocarbons in the surface soil of Shanghai,China:concentrations,distribution and sources[J].Organic Geochemistry,2010,41(4):355-362.
[2] HALSALL C J,LEE R G M,COLEMAN P J,et al.PCBs in U.K.urban air[J].Environmental Science&Technology,1995,29(9):2368-2376.
[3] GUSTAFSON K E,DICKHUT R M.Particle/gas concentrations and distributions of PAHs in the atmosphere of Southern Chesapeake Bay[J].Environmental Science&Technology,1997,31(1):140-147.
[4] DIAMOND M L,GINGRICH S E,FERTUCK K.Evidence for organic film on an impervious urban surface:characterization and potential teratogenic effects[J].Environmental Science&Technology,2000,34(14):2900-2908.
[5] DIAMOND M L,PRIEMER D A,LAW N L.Developing a multimedia model of chemical dynamics in an urban area[J].Chemosphere,2011,44(7):1655-1667.
[6] BEASLEY G,KNEALE P.Reviewing the impact of metals and PAHs on macroinvertebrates in urban watercourses[J].Progress in Physical Geography,2002,26(2):236-270.
[7] HOFFMAN E J,MILLS G L,LATIMER J S,et al.Urban runoff as a source of polycyclic aromatic hydrocarbons to coastal waters[J].Environmental Science&Technology,1984,18(8):580-587.
[8] 李恭臣,夏星辉,王然,等.黄河中下游水体中多环芳烃的分布及来源[J].环境科学,2006,27(9):1738-1743.[LI G C,XIA X H,WANG R,et al.Pollution of polycyclic aromatic hydrocarbons (PAHs) in middle and lower reaches of the Yellow River[J].Environmental Science,2006,27(9):1738-1743.]
[9] 吴瑞杰.郑州市大气颗粒物PM2.5和PM10的特性研究[D].郑州:郑州大学硕士学位论文,2011:27-51.[WU R J.Chemical Characterization of PM2.5 and PM10 atmospheric aerosols in Zhengzhou,China[D].Zhengzhou:Master Dissertation of Zhengzhou University,2011:27-51.]
[10] 蒋煜峰,胡雪菲,王蓓蕾,等.兰州市西固区土壤中PAHs污染特征及来源解析[J].环境科学研究,2014,27(10):1164-1171.[JIANG Y F,HU X F,WANG B L,et al.Levels,source identification and contamination characteristics of PAHs in soils from Xigu district in Lanzhou,northwestern China[J].Research of Environmental Sciences,2014,27(10):1164-1171.]
[11] 潘苏红,林田,李军,等.居室玻璃表面有机质与多环芳烃分布规律研究[J].中国环境科学,2010,30(8):1021-1025.[PAN S H,LIN T,LI J,et al.Concentration and distribution of organic matter and Polycyclic aromatic hydrocarbons (PAHs) on window glass surface[J].China Environmental Science,2010,30(8):1021-1025.]
[12] UNGER M,GUSTAFSSON Ö.PAHs in Stockholm window films:evaluation of the utility of window film content as indicator of PAHs in urban air[J].Atmospheric Environment,2008,42(22):5550-5557.
[13] 朱利中,王静,江斌焕.厨房空气中PAHs污染特征及来源初探[J].中国环境科学,2002,22(2):142-145.[ZHU L Z,WANG J,JIANG B H.Prelimilary exploration of features and sources of PAHs pollution in air of kitchen[J].China Environmental Science,2002,22(2):142-145.]
[14] 毛婷,路勇,姜洁,等.气相色谱/质谱法测定烧烤肉制品中15种欧盟优控多环芳烃[J].分析化学研究报告,2010,38(10):1439-1444.[MAO T,LU Y,JIANG J,et al.Analysis of 15 European priority polycyclic aromatic hydrocarbons in grilled meat samples using gas chromatography coupled with mass spectrometry[J].Chinese Journal of Analytical Chemistry,2010,38(10):1439-1444.]
[15] 朱利中,王静,杜烨,等.汽车尾气中多环芳烃(PAHs)成分谱图研究[J].环境科学,2003,24(3):26-29.[ZHU L Z,WANG J,DU Y,et al.Research on PAHs fingerprints of vehicle discharges[J].Environmental Science,2003,24(3):26-29.]
[16] 朱先磊,刘维立,卢妍妍,等.民用燃煤、焦化厂和石油沥青工业多环芳烃源成分谱的比较研究[J].环境科学学报,2002,22(2):199-203.[ZHU X L,LIU W L,LU Y Y,et al.A Comparison of PAHs source profiles of domestic coal combustion,coke plant and petroleum asphalt industry[J].Acta Scientiae Circumstantiae,2002,22(2):199-203.]
[17] WANG X T,MIAO Y,ZHANG Y,et al.Polycyclic aromatic hydrocarbons (PAHs) in urban soils of the megacity Shanghai:occurrence,source apportionment and potential human health risk[J].Science of the Total Environment,2013,447:80-89.
[18] TSAI P J,SHIH T S,CHEN H L,et al.Assessing and predicting the exposures of polycyclic aromatic hydrocarbons (PAHs) and their carcinogenic potencies from vehicle engine exhausts to highway toll station workers[J].Atmospheric Environment,2004,38(2):333-343.
[19] YU Y P,YANG Y,LIU M,et al.PAHs in organic film on glass window surfaces from central Shanghai,China:distribution,sources and risk assessment[J].Environmental Geochemistry and Health,2014,36(4):665-675.
[1] 刘伟亚, 刘敏, 杨毅, 陆敏, 侯立军, 于英鹏, 汪青. 上海市多环芳烃排放清单构建及排放趋势预测[J]. 长江流域资源与环境, 2015, 24(06): 1003-1011.
[2] 葛成军, 俞花美. 南京市典型工业区耕地中多环芳烃源解析[J]. 长江流域资源与环境, 2009, 18(9): 843-.
[3] 罗世霞 朱淮武 张笑一 关小满. 红枫湖地表水中多环芳烃的分布及来源[J]. 长江流域资源与环境, 2009, 18(5): 466-.
[4] 许峰, 祁士华, 高媛, 邢新丽. 绵阳市代表性点位土壤多环芳烃剖面分布特征[J]. 长江流域资源与环境, 2009, 18(2): 192-.
[5] 舒卫先,李世杰. 江苏天目湖表层沉积物中多环芳烃污染特征与来源[J]. 长江流域资源与环境, 2009, 18(1): 27-.
[6] 欧冬妮,刘 敏,程书波,许世远,侯立军,高 磊. 河口滨岸悬浮颗粒物中多环芳烃分布与风险评价[J]. 长江流域资源与环境, 2007, 16(5): 620-620.
[7] 葛成军,安 琼,董元华,俞花美. 南京某地农业土壤中有机污染分布状况研究[J]. 长江流域资源与环境, 2006, 15(3): 361-365.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 宋玉芝,秦伯强, 高光. 附着生物对富营养化水体氮磷的去除效果[J]. 长江流域资源与环境, 2009, 18(2): 180 .
[2] 曾慧卿. 近40年气候变化对江西自然植被净第一性生产力的影响[J]. 长江流域资源与环境, 2008, 17(2): 227 .
[3] 刘滨谊,刘 琴. 服务于城市旅游形象的景观规划——以南京市为例[J]. 长江流域资源与环境, 2006, 15(2): 164 -168 .
[4] 梁常德,龙天渝,李继承,刘腊美. 三峡库区非点源氮磷负荷研究[J]. 长江流域资源与环境, 2007, 16(1): 26 -30 .
[5] 吴丰林,周德民,胡金明. 基于景观格局演变的城市湿地景观生态规划途径[J]. 长江流域资源与环境, 2007, 16(3): 368 .
[6] 屈 璠,刘 敏,侯立军,许世远,刘巧梅,欧冬妮. 潮汐循环影响下上覆水环境因子和氮营养盐的变化及其相关关系[J]. 长江流域资源与环境, 2007, 16(3): 345 .
[7] 一之濑俊明 大坪国顺 景元书. 依据经济水平建立的华中—华南粮食运输模型[J]. 长江流域资源与环境, 2009, 18(3): 217 -221 .
[8] 刘小丽, 沈 芳, 朱伟健, 刘 曦. MERIS卫星数据定量反演长江河口的悬沙浓度[J]. 长江流域资源与环境, 2009, 18(11): 1026 .
[9] 刘扬扬, 张行南, 徐双全, 倪斐. 长江口滩涂地形冲淤分析研究[J]. 长江流域资源与环境, 2010, 19(11): 1314 .
[10] 赵 爽| 王慧敏| 仇 蕾. 工业水环境监管契约研究[J]. 长江流域资源与环境, 2011, 20(10): 1279 .