贵州省三岔河流域水化学特征及其控制因素

doi:10.11870/cjlyzyyhj201607014

长江流域资源与环境 >> 2016, Vol. 25 >> Issue (07): 1121-1128.doi: 10.11870/cjlyzyyhj201607014

贵州省三岔河流域水化学特征及其控制因素

侯祎亮^1,2, 安艳玲^1,2, 吴起鑫^1,2,3, 吴旌滔^1,2, 黄娟², 段少琼^1,2, 刘霄^1,2

1. 贵州大学喀斯特环境与地质灾害防治重点实验室, 贵州贵阳 550025;
2. 贵州大学资源与环境工程学院, 贵州贵阳 550025;
3. 中国科学院地球化学研究所环境地球化学国家重点实验室, 贵州贵阳 550002

收稿日期:2016-03-17 修回日期:2016-05-18 出版日期:2016-07-20
通讯作者: 安艳玲 E-mail:re.ylan@gzu.edu.cn
作者简介:侯祎亮(1989~),男,硕士研究生,主要从事流域水环境与水化学方面研究.E-mail:houyl89@163.com
基金资助:
博士后基金（No.2014M552388）；贵州省科技厅重点实验室建设项目（黔科合SY字3133,黔科合计Z字4012）3133,QiankeheZ4012）贵州省自然科学基金（黔科合J字2130,黔科合J字2298）2130,QiankeheJ2298）贵州大学研究生创新基金项目（研理工2015077）

HYDROCHEMICAL CHARACTERISTICS IN THE SANCHAHE RIVER BASIN AND THE POSSIBLE CONTROLS

HOU Yi-liang^1,2, AN Yan-ling^1,2, WU Qi-xin^1,2,3, WU Jing-tao^1,2, HUANG Juan², DUAN Shao-qiong^1,2, LIU Xiao^1,2

1. Key Laboratory of Karst Environment and Geohazard Prevention, Guizhou University, Guiyang 550025, China;
2. College of Resources and Environmental Engineering, Guizhou University, Guiyang 550025, China;
3. State Key Laboratory of Environment Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China

Received:2016-03-17 Revised:2016-05-18 Online:2016-07-20
Supported by:
Postdoctoral Fund(No.2014M552388);Key Laboratory Construction Project of Guizhou Province(Qiankehe SY20133133, Qiankehe Z20124012);The Natural Science Foundation of Guizhou Province(QiankeheJ20132130, Qiankehe J20132298);Guizhou University Graduate Innovation FundProject(Yanligong 2015077)

摘要/Abstract

摘要： 对乌江源区三岔河流域枯水期和丰水期河水样品离子浓度及组成特征分析表明，河水主要的阴阳离子分别是HCO₃^-和Ca²⁺，分别占到总阴离子量的55%和总阳离子量的70%，与喀斯特地区流域相似。主要离子的时空分布的对比分析表明，Ca²⁺、Mg²⁺、Na⁺、HCO₃^-、Cl^-枯水期浓度略高于丰水期，而K⁺、SO₄^2-、NO₃^-两期浓度变化相对较小；空间分布的多样化，反映了不同小流域在地质背景、生态环境、人为活动等方面的差异对河水离子的影响。通过Gibbs图分析表明，研究区河水水化学主要受到岩石风化的影响，通过阴阳离子三角图分析表明，研究区河水水化学主要受到碳酸岩盐的影响，并且硫酸广泛参与到岩石风化中，人为活动对流域水化学组成也有一定影响。

关键词: 三岔河, 水化学, 离子来源, 影响因素

Abstract: The analysis of ion concentration and composition characteristics was conducted based on samples from the Sanchahe River Basin, which were collected in dry and wet seasons from the Wujiang source area. The results showed that the dominate anion and cation were HCO₃^-and Ca²⁺ in the samples, accounting for 55% and 70% of the total anions and total cations, respectively, suggesting that the ion composition was similar with that of the karst area river basins. The comparison of temporal variations of the concentrations of major ions showed that, the concentrations of Ca²⁺、Mg²⁺、Na⁺、HCO₃^-、Cl^- in dry seasons were slightly higher than they were in wet seasons, while the concentrations of K⁺、SO₄^-2、NO₃^- were almost the same in these two seasons. And the spatial distribution types of the ions were diversified, showing that different small basins have different geological background, ecological environment, and different human activities, all of these could affect the concentration and composition of water ions. The Gibbs diagram indicated that the river water chemistry was mainly influenced by rock weathering. Triangle diagram showed that the river water chemistry was mainly affected by the carbonate rock, and sulfuric acid was widely involved in the rock weathering. Human activities also have some influences on the composition of water chemistry.

Key words: Sanchahe River, water chemistry, ion sources, impact factors

中图分类号:

侯祎亮, 安艳玲, 吴起鑫, 吴旌滔, 黄娟, 段少琼, 刘霄. 贵州省三岔河流域水化学特征及其控制因素[J]. 长江流域资源与环境, 2016, 25(07): 1121-1128.

HOU Yi-liang, AN Yan-ling, WU Qi-xin, WU Jing-tao, HUANG Juan, DUAN Shao-qiong, LIU Xiao. HYDROCHEMICAL CHARACTERISTICS IN THE SANCHAHE RIVER BASIN AND THE POSSIBLE CONTROLS[J]. RESOURCES AND ENVIRONMENT IN THE YANGTZE BASIN, 2016, 25(07): 1121-1128.

参考文献

[1] MEYBECK M. Global occurrence of major elements in rivers[J]. Treatise on Geochemistry, 2003, 5(1):207-223.
[2] 陶贞,高全洲,王振刚,等.湿热山地丘陵流域化学风化过程的碳汇估算[J].科学通报, 2011, 56(26):2188-2197.[TAO Z, GAO Q Z, WANG Z G, et al. Estimation of carbon sinks in chemical weathering in a humid subtropical mountainous basin[J]. Chinese Science Bulletin, 2011, 56(26):2188-2197.]
[3] GIBBS R J. Water chemistry of the Amazon River[J]. Geochimica et Cosmochimica Acta, 1972, 36(9):1061-1066.
[4] CHEN J S, WANG F Y, XIA X H, et al. Major element chemistry of the Changjiang (Yangtze River)[J]. Chemical Geology, 2002, 187(3):231-255.
[5] ZHANG J, HUANG W W, LETOLLE R, et al. Major element chemistry of the Huanghe (Yellow River), China-weathering processes and chemical fluxes[J]. Journal of Hydrology, 1995, 168(1):173-203.
[6] 韩贵琳,刘丛强.贵州乌江水系的水文地球化学研究[J].中国岩溶, 2000, 19(1):37-45.[HAN G L, LIU C Q. Hydrogeochemistry of Wujiang River water in Guizhou province[J]. Carsologica Sinica, 2000, 19(1):37-45.]
[7] SHEIKH J A, JEELANI G, GAVALI R S, et al. Weathering and anthropogenic influences on the water and sediment chemistry of Wular Lake, Kashmir Himalaya[J]. Environmental Earth Sciences, 2014, 71(6):2837-2846.
[8] LI S Y, ZHANG Q F. Major ion chemistry and weathering processes of the Danjiangkou Reservoir, China[J]. Hydrological Sciences Journal-Journal Des Sciences Hydrologiques, 2010, 55(8):1385-1395.
[9] 张芸,吕宪国,杨青.三江平原典型湿地水化学性质研究[J].水土保持学报, 2005(1):184-187.[ZHANG Y, LU X G, YANG Q.Water hydrochemistry of typical wetland in Sanjiang Plain[J]. Journal of Soil and Water Conservation, 2005(1):184-187.]
[10] XIAO J, JIN Z D, ZHANG F, et al. Major ion geochemistry of shallow groundwater in the Qinghai Lake catchment, NE Qinghai-Tibet Plateau[J]. Environmental Earth Sciences, 2012, 67(5):1331-1344.
[11] 吴起鑫,韩贵琳,陶发祥,等.西南喀斯特农村降水化学研究:以贵州普定为例[J].环境科学, 2011, 32(1):26-32.[WU Q X, HAN G L, TAO F X, et al. Chemical characterization of rainwater in a Karst rural site:A case study of Puding, China[J]. Environmental Science, 2011, 32(1):26-32.]
[12] 韩贵琳,刘丛强.贵州喀斯特地区河流的研究——碳酸盐岩溶解控制的水文地球化学特征[J].地球科学进展, 2005(4):394-406.[HAN G L, LIU C Q. Hydrogeochemistry of rivers in Guizhou Province, Chian:constraints on crustal weathering in karst terrain[J]. Advances in Earth Science, 2005(4):394-406.]
[13] 李思亮,韩贵琳,张鸿翔,等.硫酸参与喀斯特流域(北盘江)风化过程的碳同位素证据[J].地球与环境, 2006(2):57-60.[LI S L, HAN G L, ZHANG H X, et al. Carbon isotopic evidence for the involvement of sulfuric acid in carbonate weathering of Beipan River catchment[J]. Earth and Environment, 2006(2):57-60.]
[14] AN Y L, HOU Y L, WU Q X, et al. Chemical weathering and CO₂ consumption of a high-erosion-rate karstic river:A case study of the Sanchahe River, southwest China[J]. Chinese Journal of Geochemistry, 2015, 34(4):601-609.
[15] 焦树林,罗福家,梁虹,等.乌江源区阳长流域化学侵蚀作用的碳汇效应[J].水土保持学报, 2012, 26(5):44-47.[JIAO S L, LUO F J, LIANG H, et al. The atmospherical CO₂ consumption in the chemical weathering processes of the Yangchang hydrological stations basin in Wujiang River source drainage basins area[J]. Journal of Soil and Water Conservation, 2012, 26(5):44-47.]
[16] GAILLARDET J, DUPRÉ B, LOUVAT P, et al. Global silicate weathering and CO₂ consumption rates deduced from the chemistry of large rivers[J]. Chemical Geology, 1999, 159(1-4):3-30.
[17] 吕婕梅,安艳玲,吴起鑫,等.贵州清水江流域丰水期水化学特征及离子来源分析[J].环境科学, 2015(5):1565-1572.[LU J M, AN Y L, WU Q X, et al. Hydrochemical characteristics and sources of Qingshuijiang River Basin at wet season in Guizhou province[J]. Environmental Science, 2015(5):1565-1572.]
[18] 罗进,安艳玲,吴起鑫,等.赤水河中下游冬季河水化学空间分布特征分析[J].地球与环境, 2014, 42(3):297-305.[LUO J, AN Y L, WU Q X, et al. Spatial distribution of surface water chemical components in the middle and lower reaches of the Chishui River Basin[J]. Earth and Environment, 2014, 42(3):297-305.]
[19] 吴起鑫,韩贵琳,李富山,等.珠江源区南、北盘江丰水期水化学组成特征及来源分析[J].环境化学, 2015, 34(7):1289-1296.[WU Q X, HAN G L, LI F S, et al. Chractristic and soursce analysis of major ions in Nanpanjiang and Beipanjiang at the upper pearl river during the wet season[J]. Environmental Chemistry, 2015, 34(7):1289-1296.]
[20] HAN G L, LIU C Q. Water geochemistry controlled by carbonate dissolution:A study of the river waters draining karst-dominated terrain, Guizhou Province, China[J]. Chemical Geology, 2004, 204(1-2):1-21.
[21] XU Z F, LIU C Q. Water geochemistry of the Xijiang basin rivers, South China:Chemical weathering and CO₂ consumption[J]. Applied geochemistry, 2010, 25(10):1603-1614.
[22] 李甜甜,季宏兵,江用彬,等.赣江上游河流水化学的影响因素及DIC来源[J].地理学报, 2007, 62(7):764-775.[LI T T, JI H B, JIANG Y B, et al. Hydro-geochemistry and the sources of DIC in the upriver tributaries of the Ganjiang River[J]. Acta Geographica Sinica, 2007, 62(7):764-775.]
[23] 万洪涛,谢传节,杨勇,等.贵州后寨河喀斯特小流域水化学特征[J].中国岩溶, 1999(4):45-52.[WAN H T, XIE C J, YANG Y, et al. The hydrochemical characteristics of Houzhai small karst basin, Guizhou[J]. Carsologica Sinica, 1999(4):45-52.]
[24] 蒙海花,王腊春.喀斯特流域水体中离子时空变化特征[J].水资源保护, 2007(5):1-5+10.[MENG H H, WANG L C. Spatial-temporal characteristics of the ions in Karst Basin[J]. Water Resources Protection, 2007(5):1-5+10.]
[25] GIBBS R J. Mechanisms controlling world water chemistry[J]. Science, 1970, 170(3962):1088-1090.
[26] 解晨骥,高全洲,陶贞.流域化学风化与河流水化学研究综述与展望[J].热带地理, 2012, 32(4):331-337.[XIE C J, GAO Q Z, TAO Z. Review and perspectives of the study on chemical weathering and hydrochemistry in river basin[J]. Tropical Geography, 2012, 32(4):331-337.]
[27] 张红波,何师意,于奭,等.桂江流域河流水化学特征及影响因素[J].中国岩溶, 2012, 31(4):395-401.[ZHANG H B, HE S Y, YU S, et al. Hydrochemical characteristics and influencing factors of the river water in the Guijiang[J]. Carssologica Sinica, 2012, 31(4):395-401.]
[28] 原雅琼,何师意,于奭,等.柳江流域柳州断面水化学特征及无机碳汇通量分析[J].环境科学, 2015, 36(7):2437-2445.[YUAN Y Q, HE S Y, YU S, et al. Hydrochemical characteristics and the dissolved inorganic carbon flux in Liuzhou section of Liujiang Basin[J]. Environmental Science, 2015, 36(7):2437-2445.]
[29] SUN H G, HAN J T, LI D, et al. Chemical weathering inferred from riverine water chemistry in the lower Xijiang Basin, South China[J]. Science of The Total Environment, 2010, 408(20):4749-4760.
[30] 李军,刘丛强,李龙波,等.硫酸侵蚀碳酸盐岩对长江河水DIC循环的影响[J].地球化学, 2010(4):305-313.[LI J, LIU C Q, LI L B, et al. The impacts of chemical weathering of carbonate rock by sulfuric acid on the cycling of dissolved inorganic carbon in Changjiang River water[J]. Geochimica, 2010(4):305-313.]
[31] 刘丛强,蒋颖魁,陶发祥,等.西南喀斯特流域碳酸盐岩的硫酸侵蚀与碳循环[J].地球化学, 2008, 37(4):404-414.[LIU C Q, JIANG Y K, TAO F X, et al. Chemical weathering of carbonate rocks by sulfuric acid and the carbon cycling in Southwest China[J]. Geochimica, 2008, 37(4):404-414.]
[32] 于奭,孙平安,杜文越,等.人类活动影响下水化学特征的影响:以西江中上游流域为例[J].环境科学, 2015(1):72-79.[YU S, SUN P A, DU W Y, et al. Effect of hydrochemistry characteristics under impact of human activity:A case study in the upper reaches of the Xijiang River Basin[J]. Environmental Science, 2015(1):72-79.]
[33] 王亚平,王岚,许春雪,等.长江水系水文地球化学特征及主要离子的化学成因[J].地质通报, 2010, 29(2):446-456.[WANG Y P, WANG L, XU C X, et al. Hydro-geochemistry and genesis of major ions in the Yangtze River, China[J]. Geological bulletin of China, 2010, 29(2):446-456.]

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